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No, sodium bisulfate (NaHSO4) cannot be prepared by mixing sodium sulfate (Na2SO4) with hydrochloric acid (HCl), because both sulfuric acid and hydrochloric acids are "strong" acids (the H+ will completely dissociate from the anion in solution). If there is enough sodium to bind to the sulfate ions (2 sodiums per sulfate), then the H+ ions will gladly let them do so.

So, NaHSO4 must be produced from sulfuric acid (H2SO4). One method is adding just enough sodium hydroxide (NaOH) so that the number of sodium ions is equal to the number of sulfate ions:

H2SO4 + NaOH ---> NaHSO4 + H2O

The sodium will displace one of the hydrogens, but there's not enough to displace both.

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15y ago

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