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Can you have a negative pH?

Updated: 8/10/2023
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10y ago

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No, because of the way pH is defined. It is the negative log of the Hydrogen ion concentration. In water the extreme values of hydrogen ions are 0 and 14 corresponding with 1 and 1*10-14. Any higher hydrogen ions than this and the solution would become electrostatically positive.

Ironnica: please have a look at the associated link i have included and respond

If we assume that ph is a matter of hydrogen ion concentrations in water (as it 'always' is) then we cannot have a negative ph value. It comes down to the electro-static behavior of water.

But if we are willing to state that ph is simply a matter of hydrogen atom concentrations then, yes, we could have negative ph values.

For example if we were to have one liter of hydrogen gas at STP then we would have 44 moles of hydrogen gas per liter. Which would give 88 moles of hydrogen atoms per liter, making a concentration of 88M.

The negative log of 88 is -1.95.

But discussion ph outside of a aquatic situation is kind of silly.

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12y ago
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10y ago

Yes. The pH scale is open-ended. The strongest acid is fluoroantimonic acid, formula H2FSbF6. This stuff can easily produce pH -16.

Problem is, pH meters are not usually designed to measure these values, and buffers for calibrating meters don't go that low.

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