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At 20o C aniline's rate of solubility in water is 3.6g/mL. So, aniline mixes with water unlike kerosene which forms a layer above the water.

Separating funnel is used to separate two immiscible liquids and cannot separate miscible liquids. Hence, we cannot separate water and aniline using separating funnel.

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Q: Can you separate water and Aniline using separating funnel?
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