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Yes, with someone who wants the paper and not the silver bar and, of course, depending on how many certificates you have. But no, not if you're asking about the federal reserve exchanging the bills for bars. Some collectors might trade bars for paper, depending on how much paper you have, but the paper currency is no longer valued at a rate greater than its face value. Collector rates vary based on condition and other unique specifics to the bills in question but the US went off the silver standard when the silver coins became more valuable as bullion than the face value of the minted coin.

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