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No, it has to do with the insulation rating of the individual cords. 12 volts can be used on a voltage rating of 120 volts. But 120 volts can not be used on a 12 volt rated cord. As a point of interest most power cords have an insulation rating of 300 volts.

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Q: Can you use a 12v 60hz 210 va power cord to replace a 120v 60hz 150w cord?
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