Yes- you must take it to the move relearner in Pastoria City with a Heart Scale.
lvl 59
it does not even learn fire blast it learns flare blitz instead
Level 49
At Lvl. 49.
It cannot learn Brave Bird in Pokemon Ruby, Sapphire, or Emerald.
blaziken can learn ice punch
Neither Murkrow or Honchkrow are able to learn Brave Bird.
Ah, BraveBird. The best flying type attack, even though it has big recoil damage. Lets see...... These Pokemon learn it through Level Up: Ho-oh= Level 15 Blaziken= Level 49 Starly= Level 37 Staravia= Level 43 Staraptor= Level 49 These Pokemon learn it through breeding= Pidgey Zubat Doduo Murkow Tailow Skarmory (sorry about not listing the fathers for breeding. Bulbapedia is down ATM and i cant check what fathers. -.-')
Blaziken does NOT learn flamethrower. but torchiccan. at level 42 i think!
Blaziken cannot learn Flamethrower by leveling up but it can learn Flamethrower via the TM 35. Blaziken's pre-evolved form Torchic can learn Flamethrower at level 43.
Taillow cannot learn Brave Bird. To teach Brave Bird you need to breed Taillow.
what i learnd OS with my blaziken it learn sky uppercut at lvl 57but that is what i think