No. He served in the Washington presidency and then was president after Washington.
George Washington, John Adams, Thomas Jefferson, James Madison, James Monroe, John Quincy Adams.
I am not sure what you mean by "youngest". The first president with a college degree was John Adams, the second president. Monroe was 16 when he first went to college; John Quincy Adams was 14 when he first started taking classes at Leyden.
Here are the first six presidents: # George Washington # John Adams # Thomas Jefferson # James Madison # James Monroe # John Quincy Adams
George Washington (1789-97) vice president-john Adams John Adams (1797-1801) Thomas Jefferson (1801-09) James Madison (1809-17) James Monroe (1817-25) John Quincy Adams (1825-29)
James Monroe
Goerge Washington John Adams James Madison James Monroe (these are in order) James Monroe
James
Thomas Jefferson, John Adams, and James Monroe died on July 4th.
S. S. President Monroe
The first 5 presidents of the United States were; George Washington, John Adams, Thomas Jefferson, James Madison, and James Monroe.
Monroe served as governor of Virginia before he was the US president.
James Buchanan, who served as Secretary of State for James Polk was the most recent Secretary of State to later become President. (Other former Secretaries who later became President were Martin Van Buren, John Quincy Adams, James Monroe , James Madison and Thomas Jefferson.)