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When they fill their outermost energy levels. Metals will WANT more electrons and Non-Metals will have EXTRA electrons to give. So in a way, Metals will actually fill their outermost energy levels while Non-Metals will empty them; all with the goal of having a FULL valency shell which is stable. This is the basis for ionic bonding.

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How does the number of electrons in outer energy levels relate to the position of an element in the periodic table?

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