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Pure baking soda does not have a pH.

pH is the negative logarithm of the concentration of hydrogen ions in an aqueous solution (a solution where water is the solvent).

But if you have baking soda, or any alkaline substance, in a higher concentration (i.e. more dissolved in the same amount of water) the pH will be higher, if it is in a lower concentration, the pH will be lower.

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Q: Does a solution of baking soda and water have a lower pH that baking soda alone?
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