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water have inter molecular hydrogen bonding whereas in methanol there is intra molecular hydrogen bonding.the oxygen atom and hydrogen of other molecule have electrostatic force of attraction in water and forms bridge between each other and form an associated structure thus it has more b.p

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Q: Does methanol have a higher boiling point than water?
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Why methane mercaptan has a lower boiling point than methanol even though methyl mercaptan has a higher molecular weight?

For the same reason that water isn't a gas. Oxygen is highly electronegative and the hydrogen bonding present in water and methanol raises the intermolecular attractive forces and results in a higher boiling point.


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