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An easy method of catching Moltres and other Legendary Pokemon outside of using the Master Ball is usage of the move False Swipe and a sleep inducing move. The move False Swipe can never reduce a Pokemon's HP lower than 1 which raises the catch rate the most by HP reduction. Next putting the Pokemon to Sleep via a move like Sleep Powder also raises their catch rate. Sleep also reduces the damage they do to your team while you're throwing Pokeballs at them. The Legendary Pokemon's catch rate chance is still rather low so you will still need to use a lot of Pokeballs.

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