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A soap is an organic molecule that has a polar/hydrophilic end and a nonpolar/hydrophobic end. The polar end typically has a hydroxyl functional group, which acts like a weak acid in water.

Hard water is water that has a relatively large solute load, typically calcium, magnesium and other metals.

When you add a soap to hard water, the metal ions in the water attach themselves to the polar end and you get a precipitate of the salt form of the soap. This inactivates the soap. However, if you add enough soap, you will effectively "soften" the water by pulling enough metal ions out of solution to still have active soap molecules in the water.

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Q: Explain why soaps can be effective in hard water if relatively large quantities of soap are added to water?
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