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These compounds are called hydrates; water is called water of crystallization.
14KMnO4 + 4C3H5(OH)3 --> 7K2CO3 + 7Mn2O3 + 5CO2 + 16H2O
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C7H16+11O2 = 7CO2+8H2O is the balanced equation for the complete combustion of heptane.