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Q: How do the constituent chemical groups determine the pI of arginine?
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Between lysine and arginine which is more basic?

arginine is more basic due to the presence of 3 NH2 groups


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Why is arginine the most basic amino acid?

Because it has a guanidinium group. Guanidinium groups have a pKa of 12.48, and thus can remain positively charged in most pH conditions, rendering them strongly basic.