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First you must win your first gym badge at Striaton City. After the battle make sure you heal your Pokemon at the PokeCenter. When you leave the poke center head to the right until you enter the next area (where you receive one of your Pansear variations). Use cut, and enter the door way. You will then see an event involving Team Plasma. After that head back to Fennel's house and he will give you the C-Gear equipment. After that you will have access to the Union Room.

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Q: How do you activate the Union room in Pokemon White?
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