To;
The Reverend and Mrs (Insert name)
Mr John and (Rev) Mrs Jane Jones
If the letter/invitation is primarily to the reverend but also her husband: Rev. Mary Smith and Mr. John Smith If the letter/invitation is primarily to the husband but includes the wife: Mr. John Smith and Rev. Mary Smith If it is strictly a business letter and not church related: Mr. & Mrs. John Smith
To the Rev. John & Jane Alforth.
You can address a retired colonel as "Colonel (Last Name)" and his wife as "Mrs. (Last Name)" or "Colonel (Last Name) and Mrs. (Last Name)" in the salutation of a letter.
Dear Mr. John and Rev. Sally Smith,
To the wife only, just as Mrs. She has no title of her own.
The best way to address your letter to a Minister is to Reverend and Mrs. _______
Govenor and Mrs. Beebe
What is the proper etiquette to addressing a Reverend in a letter?
Captain and Mrs.....
"The Rev. and Mrs. (his first and last name)" would be the correct way to address an envelope to a pastor and his wife.
If you are referring to The Rev of Avenged Sevenfold, he was married to Leana MacFadden (aka Leana Silver).