Currently there is no legit way for a Pichu to know Volt Tackle in Pokémon Black or Pokémon White except through attaching a Light Ball to a Pikachu and breeding it with a compatible Pokémon in any of the 4th Generation games which are Pokémon Diamond, Pokémon Pearl, Platinum, HeartGold and SoulSilver and then transferring the newly hatched Pichu over to either Black or White.
get two pikas go to 4th isle have one hold light ball and the egg when it hatches will have a pichu that knows volt tackle
breed pikachu or richu with ditto or another pikachu/richu. if its a female pikachu or richu, make it hold a light ball and the bred pichu knows volt tackle.
not sure but probably a ditto
i dont really know in the game you need to breed with a pikachu with a light ball and pichu knows it they change stuff in the show
you have to breed a female pikachu or raichu while it holds a light ball. the egg will hatch into a pichu that knows volt tackle.
Pichu learns Volt Tackle by attaching a Light Ball to a female Pikachu or Raichu and breeding it with a male compatible in order to hatch a Pichu that knows Volt Tackle or you could opt to attach a Light Ball to either gender and use Ditto in order to breed them so that a Pichu Egg will be created that will know Volt Tackle however this is only possible in Pok
Thunder - Use TM25 or evolve a Pikachu that knows it. Thunderbolt -Lv1.Volt Tackle - Evolve a Pichu that knows it into a Pikachu then a Raichu.Pichu learns Volt Tackle if you breed a Pikachu♀ holding a Light Ball. The Egg will hatch into a Pichu which will know Volt Tackle. Pikachu learns Thunder at Lv45.
If you breed a Female Pikachu holding a Light Ball with a Male from the Fairy Egg group,(Example, Cherrim, Clefairy) you will receive a Pichu that knows the move Volt Tackle. Then evolve it. Now you have a Pikachu that knows Volt Tackle!
You cannot make pikachu learn volt tackle, you have to breed pikachu's whilst they hold the light ball to then get an egg that will hatch into a pichu that knows volt tackle.
If your talking about the light ball to get a pichu that knows volt tackle to get it you have to go into the safari zone and catch as many feamale pikachu as you can. Eventually one will have a light ball. Then if you breed the pikachu you'll get a pichu with volt tacle. But be warned. Once you breed it the light ball disappears forever. You can find another one by looking for more female pikachu's though. I hope this helped.
In Pokémon XD: Gale of Darkness, you can get Pikachu to learn Volt Tackle by first obtaining a Pichu that knows the move. To do this, you need to breed a Pikachu or Raichu with a Pokémon that knows Volt Tackle, such as a female Pikachu or Raichu with a male Electrike or Manectric. Once you have the Pichu, level it up until it evolves into Pikachu, and it will retain Volt Tackle.
Pikachu can only learn Iron Tail by TM. It is TM 23 in Generation IV.