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You can't catch a Phione on Pokemon Pearl. But you can receive one.

  1. Get a Manaphy (Pokemon Ranger series or Pokemon Event)
  2. Get a Ditto (Route 218 using PokeRadar)
  3. Put them in the Daycare (Sandgem Town)
  4. Get the egg they make (talk to the man outside the Daycare looking east)
  5. Hatch the egg (bring a Magcargo along it'll be faster)
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14y ago

What else can I help you with?