chemical dryer - a very hygroscopic dessicant
Distillation. Ethanol can be easily collected from water using distillation up to 97% purity.
You would use distillation, in which the ethanol and water will boil at different temperatures.
Distillation is based on the difference between boiling points of liquids. Ethanol is separated first.The distillation is possible only to an ethanol concentration of 95,63 % because an azeotropic mixture is formed.
They have different boiling points
I dont think so because ethanol, containing an OH group is readily soluble in water.
I hesitate to say that it literally can't be done, but ethanol dissolves things that water doesn't and the whole point of steam distillation is that the thing you're steam distilling needs to not be very soluble in water, so at best there's no real benefit from adding ethanol and at worst you can't separate your desired product out of the ethanol/water mix.If you're not trying to separate it out, then ... you're not really doing a "steam distillation", you're doing an extraction. Gin, for example, is made by allowing the vapors from an ordinary distillation of ethanol/water (to increase ethanol content) to pass over/through substances like juniper berries to pick up some of the essential oils from these and give the resultant product flavor.
While the distillation is going on ,at 94.6% ethanol-water mixture forms an azeotrope which hampers further distillation.So ethanol cannot be made 100% pure.But concentration of ethanol can be increased by breaking the azeotrope by addition of benzene in large amount.
The liquid that boils at a lower temperature will become a gas first and this will be the first one that you collect. Water boils at 100 degrees C and methanol boils at 64.7 degrees C so you will collect methanol first and then water.
Ethanol and water can be separated by fractional distillation. Fractional distillation separates liquid mixtures with different boiling points. Ethanol boils at a lower temperature than water. However, it forms a boiling azeotrope with water (azeotropes occur when solvent mixtures boil at a lower temperature than the component solvents). The azeotrope boils at 77.85 degrees, whereas pure ethanol boils at 78.4 degrees. The azeotrope is 96% ethanol and 4% water by volume. This is the maximum concentration of ethanol that can be achieved by simple distillation. Other methods of separating ethanol from water include using salts to make the water and ethanol phase-separate, using molecular sieves, using additives to change the azeotropic mixture, or distilling dry ethanol from wet ethanol that has been treated with a water-reactive metal, leaving behind the solid metal hydroxide.
Fractional distillation is used to separate liquids like water and ethanol the liquid that will come out first is ethanol because it has a lower boiling point. In industrial applications it works to separate various components like crude oil and manufactures spirits like whisky ,rum etc
A mixture of ethyl alcohol and water actually boils at a lower temperature than either pure ethanol or pure water (the word for this is azeotrope). This is why you don't see liquors higher than 190 proof; that's essentially the maximum possible ethanol concentration you can get from distillation. It is possible to get 200 proof/100% ethanol ("absolute alcohol" in chemistry jargon) but it requires a more complicated and expensive procedure than ordinary distillation. If the starting material of the distillation was more than 95% ethanol then ethanol will remain; if it was less then water will remain.
Ethanol can reach up to 99% purity, which means highest concentration. Pure Ethanol is colorless exactly like water! Any color in ethanol is because of bad distillation or additives!