you can not evolve a riolu if its level100 I'm sorry
At level 100
Truth is even if its at level 100 it won`t evolve you need to use a thuderstone.
in diamond--level 30 pearl--level 30 emearald--by trade or by level 100
It is impossible unless you need to use a stone on it.
Ok so you want to know how to evolve Riolu? This only works if you have the game on an R4. Then go to Pokemon Diamond or Pearl then go on Cheats, then go down to 'Rec items Bag Slot 1' then go on rare candies then save it. Then go on Pokemon Diamond/pearl - go on your guy and wait a minute on Bag. Then scroll through it all, then go one of the pictures at the bottom and then go to Irin Island then defeat team galactic and then you will get a Pokemon egg that hatches into Riolu. Then use your rare candies on him then it will evolve when you get to level 100 and it will evolve to Lokarewo and then you've done it!Toby, age 6
it isn't possible.. you will need to breed it and get a new one impossible!? well, i think its through happiness isn't that right? so, give it poffins or give it a massage at the lady at the house close to the gym in veilstone city
No, a level 100 Vanilish can't evolve.
no when it is level 100 you cant evolve it any more
LEVEL IT UP WITH RARE CANDIES, BUT TO GET 999 RARE CANDIES, YOU NEED TO HAVE AN ACTION REPLAY BECAUSE THERE IS NO CODE FOR LEVEL 100 POKEMON BUT THE PROBLEM IS AS SOON AS YOUR LEVELING UP YOUR POKEMON IT WILL EVOLVE INTO MONFERNO AND THEN IT WILL EVOLVE INTO INFERNAPE LEVEL 100 SO I DONT THINK YOU CAN GET CHIMCHAR LEVEL 100. ONLY FOR POKEMON DIAMOND AND PEARL
Happiny will evolve only when it has max friendship with its trainer it can be level 100 when it evolves if you don't treat it good the earliest level you can get Chansey is level 2!
well first, you have to complete amp plants dungeon. after that your riolu shuld be at level 25 - 46 to learn aura sphere. and another way is to grow riolu to level 34 to 46 and go to electivires link shop and then click on remember and it'll be there
at level 100