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If it's an element find the difference in the electronegativities. If the difference is between 0 and 0.3, then it's nonpolar-covalent. If the difference is between 0.3 and 1.7, then it's polar-covalent. If the difference is between 1.7 and 3.3, then it's ionic. For example, fluorine and cesium. F has an electronegativity of 4.0, and Cs has an electronegativity of 0.7. 4.0-0.7=3.3, so the cesium-fluorine bonding would be ionic.

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