you get your first master ball after defeating Giovanni in safron city in the biggest building.
The way to utilize the infinite Master Ball glitch is use the Master Ball in any battle with your first Pokémon and then on your second turn, switch the place of the Master Ball with any other Poké Ball.
go to jubilife and a lottery will be in a building. if first place they will give you a master ball
yes at the department store (first floor) their is a raffle if all of the numbers match you get a master ball
get it from a trade
when you beat Dialga you get the Master ball NO! It's when you beat Cyrus of Team Galactic the first time!
first you get amaster ball give the master ball to Pokemon copy that Pokemon over and over again then take the master balls from the Pokemon
master ball
After you beat Cyrus for the first time, he will give you a master ball. Also you can get one if you get 5 digits correct in the lottery.
you can get one from trading from someone else a pokemon that is HOLDING a master ball, or you can use cheats
throw a master ball throw a master ball (i dont have a master ball) from tanman07
there is no master ball in diamond and also great ball. but there is silver ball-silver ball is like a master ball.
The first master ball is found in team magma's hideout the other or others can be won by the lottery in lilycove city in the dept store.