Various remotes exist that can be programmed for different function. This site gives you the pdf manual to assist.
http://www.starchoice.com/english/customercare/techcentral/remote_controls.asp
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You can't program FXTG remote.
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You can program your DVR with a remote control.
You can't. it's not possible to program a LG remote control. The buttons are there to fool you.
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I am pretty positive that only a Chevy dealer can program the remote keyless entry device for you.