Usually when you connect your ipod to your computer it will sync with iTunes installed on your computer and it'd do the same for your new iPod.
If you have downloaded new apps on your iPod which are not on your computer, connect your iPod to the computer with the cable supplied at purchase and allow it to sync.
If not an iOS device, you must sync with computer, then sync with other iPod.
Pretty simple. Download iTunes, plug in your iPod, and click "Sync" on the computer.
Start your computer, Open Itunes. connect your ipod to your computer. It will probaly make you format your Ipod. Click Sync
You can't! Why would you think you could!
When you plug your ipod into your computer open itunes and check if the sync options are saying that it will auto sync them if not try to find the button that will auto sync them. : - }
You have to sync it because when you sync it go from your computer to your iPod but if you have an iPod touch you can download songs from your iPod's iTunes store.
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When you plug your iPod into your computer, there is a sync option with iTunes. How it works is it puts everything on your iTunes into your iPod.
you cant. you have to have the music on your computer. and after that just sync it,
When you sync a iPod touch it backs up your iPod and it can download all the songs on your computer (if you choose that option when you go to you iPod setting in music on your computer) :)