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Growlithe can learn Flamethrower at level 50 so if you evolved it into Arcanine before it reached that level, it would not be able to learn that move by itself.

You can, however, find a Move Tutor in front of the Goldenrod City Game Corner every Wednesdays and Saturdays after you beat the Elite 4 and, for 4,000 coins (Coin Case needed), you can teach your Arcanine the move.

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