There are a couple of ways:
Do 350 matches of brawls, then fight Jigglypuff and win in a brawl
Complete the Subspace Emissary, then complete Classic with any character (someone told me except Ike)
Complete Subspace Emissary, then events #1-#20, then fight and beat Jigglypuff in a brawl
Complete Subspace Emissary, then go on the stage "The Swamp" again. There will be a door (quiite late on) in there which leads to a brawl with Jigglypuff in Pokemon Stadium 2. Win, and you unlock Jigglypuff, and also add her to your Subspace Emissary Team.
You can't unlock Shaymin.
It depends on you usually it will be jigglypuff.
yes, jigglypuff will be in super smash bros brawl (unfortunately)
use jigglypuff :(
Yes but unlike the first two smash bros jigglypuff is one of the last ones to get.
Bomberman isn't in Super Smash Bros Brawl.
Beat the Subspace Emissary, go back to that mode, Go to the Swamp level and in the middle of the level, there is a door that was not there before. Enter and you fight Jigglypuff, beat it to unlock it.
play alot
You can't unlock Darkrai in Super Smash Bros. Brawl. If you hear a rumor it is obviously fake.
Rayman is not an unlockable in Super Smash Bros. Brawl.
You cannot unlock 8 bit Luigi in Super Smash Bros. Brawl. You can unlock Luigi though.
That game is not available in brawl. By blah head.