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There are a couple of ways:

Do 350 matches of brawls, then fight Jigglypuff and win in a brawl

Complete the Subspace Emissary, then complete Classic with any character (someone told me except Ike)

Complete Subspace Emissary, then events #1-#20, then fight and beat Jigglypuff in a brawl

Complete Subspace Emissary, then go on the stage "The Swamp" again. There will be a door (quiite late on) in there which leads to a brawl with Jigglypuff in Pokemon Stadium 2. Win, and you unlock Jigglypuff, and also add her to your Subspace Emissary Team.

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10y ago

What else can I help you with?