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Cosmic rays bombard the upper atmosphere (see Carbon 14 wiki):

"Carbon-14 is produced in the upper layers of the troposphere and the stratosphere by thermal neutrons absorbed by nitrogen atoms. When cosmic rays enter the atmosphere, they undergo various transformations, including the production of neutrons. The resulting neutrons (1n) participate in the following reaction: : 1n + 14N → 14C + 1H"

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