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Water almost invariably contains a selection of ions in solution. Ions are charged species that are free to move in solution, stabilised by their electron configurations and interactions with water (which usually forms solvation shells around them). Since the flow of electricity is just the net movement of electrons from one place to another, ions in water can conduct electricity, because they will move from one place to another. The charge of the ions moving from one place to the other has the same effect as the flow of electrons through the water.

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