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For practical purposes, air is an excellent thermal insulator. So any material with lots of entrained air (and through which the air cannot freely pass) will be a good thermal insulator.

The remaining conduction path through the material is along the filmy walls of the bubbles, and this path will be long and of small cross-section.

A vacuum is of course a better thermal insulator, but there are practical difficulties in making a foam of vacuum bubbles.

And there are some materials (some CFC gases) which are better thermal insulators than air, but once again there are difficulties in keeping these gases entrained in the foam bubbles.

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14y ago

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