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The Sun obtain it energy by squashing (fusing) 4 individual Hydrogen atoms together in its core to make a new, single helium atom.

The new Helium atom has slightly less mass than the 4 original hydrogen atoms and according to Einstein's famous equation E=MC2, the lost mass is converted into a HUGE amount of energy. The Sun loses mass (converts it to energy) at the rate of 4.26 million metric tons per second. This is the source of the heat and light energy of the Sun.

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