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Oxygen is an element and usually consist of 2 oxygen atoms bound i.e O2 it reacts very readily to form compounds with other element's or compounds.

Carbon is a fairly stable element is a solid and exists in the form if carbon graphite and diamond depending on the way the atoms are configured. none of these items are particularly toxic.

Carbon dioxide is a compound consisting of one carbon and 2 oxygen atoms CO2 and is poisonous to animals.

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