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Rates of reaction can be expressed depending upon their order.

For example say you have a reaction between two chemicals and the initial rate for that reaction is known :-

when:-

The concentration of one of the reactants is doubled and the other reactants concentration remains the same and the overall rate of reaction does not change - reaction is zero orderwith respect to chemical which was doubled.

The concentration of one of the reactants is doubled and other reactants concentration remains the same and the overall rate of reaction doubles - reaction is first order with respect to chemical which was doubled.

The concentration of one of the reactants is doubled and other reactants concentration remains the same and the overall rate of reaction quadruples - reaction is second order with respect to chemical which was doubled.

Zero Order

rate = k

First Order

rate = k [A] (reaction is 1st order with respect to [A] and 1st order overall)

Second Order

rate = k [A][B] (reaction is first order with respect to [A] and first order with respect to[B], reaction is second order overall)

rate = k [A]2 (reaction is second order with respect to [A] and second order overall)

Orders are simply added together in order to determine the overall order of reaction :-

rate = k [A][B][C] would be third order overall and first order with respect to each of the reactants

There are other orders of reaction, for example 2 and 3 quarter orders and third order reactions, but these are a little more complex.

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Brant Lockman

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3y ago

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