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A pound (lb) is a unit of weight. A teaspoon is a unit of volume.

One millilitre of pure (not tap) water at 3C at sea-level weighs exactly 1 gram (by definition). There are 453.59237 grams in 1 pound and so there is exactly 453.59237 ml in 1 pound.

There are 5.91939047 ml in one imperial teaspoon, and so the number of teaspoons of 3C pure water at sea level is:

453.59237 / 5.91939047 ≈ 76.628 tsp.

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