plutonium can only form from uranium in a nuclear reactor. since the last natural reactors on earth shut down about 3 billion years ago (oklo) it can't happen naturally now.
Plutonium and uranium can form alloys.
Uranium and plutonium can form alloys.
Natural plutonium exist in uranium ores in extremely traces - parts per trillion or less.
Natural isotopes of plutonium exist only in traces in uranium ores.
Plutonium and enriched uranium are different materials.Enriched uranium is uranium with a concentration of the isotope 235U greater than the natural concentration of 0,7 %.
Plutonium exist in extremely low concentrations in uranium minerals; the chemical form is probably plutonium dioxide or a complex oxide with uranium.
The atomic mass of the most common isotope of plutonium (Pu-234) is higher than the masses of the uranium natural isotopes.
Uranium is a natural chemical element, plutonium is an artificial element (but note that plutonium exist also naturally in the earth crust in extremely low concentrations). Uranium has the atomic number 92 and plutonium 94. The critical mass of uranium is greater than the critical mass of plutonium. The melting and boiling points of U and Pu are different. Uranium has an orthorombic crystalline structure; the structure of plutonium is monoclinic. And many other physical and chemical properties are different.
Plutonium is an artificial element; traces (extremely low) of plutonium isotopes of natural origin exist in uranium ores. Plutonium is used in nuclear weapons and nuclear fuels.
Yes, it is possible to recycle "burned" uranium and plutonium.
The atomic radii of uranium and plutonium are identical.
Most reactors use uranium fuel enriched slightly to about 3-4 percent U-235, in the form of uranium dioxide UO2. Some older reactors used metallic natural uranium, while some other reactors use plutonium or a plutonium-uranium mix as fuel.