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If you mean coolant in the engine oil reservoir, then yes, it is slightly possible, but very unlikely, that the engine block water jacket has developed a hole between the water and oil pathways. Other than that, the head gasket is the only place where oil and water can come in contact with each other unless your car is equipped with an engine oil cooler which is internal to the radiator (very unlikely).

If you are referring to coolant being in the radiator overflow reservoir, it is supposed to have coolant in it. When the engine is cool, the overflow reservoir should be around half full.

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Q: If radiator coolant backup in reservoir is there any reason other than blown head gasket if cap and thermostat are good?
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