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Monica and chandler was married before pheobe and mike and rachel and ross never did get married and joey never got married either so according to that Monica and chandler was married the longest but in one episode ross tells pheobe and monica, I was married to Carrol for 8 years how did I not know she was a lesbian?" so according to that ross and carrol was married the longest. Carrol is ross' first wife in which he has his son Ben by.
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