Herbalism can be combined with Alchemy to make potions, or Inscription to make glyphs and scrolls. If you are only interested in money you can have skinning or mining as your second profession and sell the proceeds.
Through the Mining and Skinning profession's.
Really only one way to make money with Herbalism and skinning. selling the stuff you gather. there are addons for WoW that will make herbalism easier by telling you where there might be some herbs to gather and another addon will create the best route for you to use. Farming, Farming, and More Farming. That is the way to go.
It depends what you want to be doing. If your want to be making gold i would suggest Herbalism and Enchanting. You can also make gold with nearly any combination, its just how you want to go about making it. If you want to save yourself gold Herbalism and Alchemy. If you want to make your own gear Skinning and Leatherworking. If you want maximum stats for raiding Jewelcrafting and Leatherworking
Glyphs can be made if you have the Inscription profession. To make glyphs you will need to either buy herbs off of the AH or have the herbalism profession (Allows you to pick you own herbs). Once you have the profession, you open up the Inscription UI and click what you want to make. If you have the materials, then the UI will make it and place it in your bags.
Hunters do not have any class abilities that unlock anything. If they have the blacksmithing profession, then they can unlock boxes and doors. Same goes for engineering.
You can get easy gold on WoW through the Mining and Skinning profession's.
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If you have the profession "Leather Working" you can use it to make items, item enchantments and other stuff.
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The quickest way to get gold in WoW is through the Mining and Skinning profession's.
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