Dr M KanagasabapathyAsst. Professor in ChemistryRajus college, Affiliated to M K UniversityRajapalayam (TN) India------------------------------------------------------------------------------------------------------Lead acid battery contains the following1. Lead PB2. Lead oxide PbO3. Sulfuric acid H2SO4During discharging Pb Oxidizes to Pb 2+ and PbO2 reduces to Pb2+ from Pb 4+PbO2 + Pb + H2SO4 = 2 PbSO4 + H2O (~ 2.0 V per cell)During charging the reverse reaction takes placePb2+ reduces to lead at cathode and another molecule of Pb2+ oxidizes to PB4+ or PbO2 by reacting with distilled water.2 Pb(2+) + H2O2 = Pb + PbO2 (> 2.0 V per cell)The important thing is the voltage for recharging should be slightly higher than the discharging voltage.During discharging the battery functions as electrochemical cell.And during charging it becomes an electrolytic cell.By,Dr M KanagasabapathyAsst. Professor in ChemistryRajus college, Affiliated to M K UniversityRajapalayam (TN) India
Lead forms the Pb2+ ion, as lead has an atomic number of 82, the Pb2+ ion has 80 electrons in total
Formula: Pb2(CO3)4
The oxidation state 4+ is not stable in PbCl4; the reaction is:Pb4+ + 2 e---------Pb2+
Lead (II) sulfate precipitate forms by:Pb2+(aq) + SO42-(aq) + [2H+]tribune --> [PbSO4]solid + [2H+]tribune
PbO2....Pb has a 4+ charge and therefore can be reduced to Pb2+ in PbO. Since it can be reduced it is an oxidizing agent.
Dr M KanagasabapathyAsst. Professor in ChemistryRajus college, Affiliated to M K UniversityRajapalayam (TN) India------------------------------------------------------------------------------------------------------Lead acid battery contains the following1. Lead PB2. Lead oxide PbO3. Sulfuric acid H2SO4During discharging Pb Oxidizes to Pb 2+ and PbO2 reduces to Pb2+ from Pb 4+PbO2 + Pb + H2SO4 = 2 PbSO4 + H2O (~ 2.0 V per cell)During charging the reverse reaction takes placePb2+ reduces to lead at cathode and another molecule of Pb2+ oxidizes to PB4+ or PbO2 by reacting with distilled water.2 Pb(2+) + H2O2 = Pb + PbO2 (> 2.0 V per cell)The important thing is the voltage for recharging should be slightly higher than the discharging voltage.During discharging the battery functions as electrochemical cell.And during charging it becomes an electrolytic cell.By,Dr M KanagasabapathyAsst. Professor in ChemistryRajus college, Affiliated to M K UniversityRajapalayam (TN) India
The chemical formula of lead tetroxide is Pb3O4.
Pb2+
Pb2+
Formula: Pb2+
It is very slightly soluble in water.In a saturated solution:[Pb2+] = 1.2x10-2 mol/L[Br-] = 2.4x10-2 mol/Lbecause [Pb2+]*[Br-]2 = Ks = 6.3*10-6 and [Br-] = 2*[Pb2+]
It is the log mean value of the inert B in counterdiffusion usually used to find a flux. P = pA1 + pB1 = pA2 + pB2 thus, pB1 = P - pA1, and pB2 = P - pA2, so: pBM = [pB2 - pB1]/ln(pB2/pB1) = [pA1 - pA2]/ln[(P-pA2)/(P-pA1)] happy engineering :)
(Pb2)O
Pb2+
Pb2(oh)
Lead forms the Pb2+ ion, as lead has an atomic number of 82, the Pb2+ ion has 80 electrons in total