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When to use back-titration instead of direct titration?

Back-titration is useful when the analyte reacts slowly or not at all with the indicator used in direct titration. It is also used when the endpoint of the direct titration is not clearly visible. Additionally, back-titration is employed when the analyte is present in very low concentrations and requires a larger amount of titrant for direct titration.


Does it take more NaOH in back titration with phenolphthalein?

Yes, it takes more NaOH in a back titration with phenolphthalein compared to a direct titration because the indicator reacts with the excess acid in the sample before the endpoint is reached. This means more base is required to neutralize the excess acid present.


What is Back titration?

A back titration is a form of titraiton in which an excess of standard reagent is added and then the reverse of the titration is carried out.


What are complexometric titration method?

Complexometric titration is a type of volumetric analysis used to determine the concentration of metal ions in a solution by forming complexes with a specific reagent. In this method, a chelating agent is typically used to form a stable complex with the metal ion, and the endpoint of the titration is usually determined using a colorimetric indicator or a pH meter. This technique is commonly employed in the analysis of a variety of metal ions in solution.


When should back titration used instead of back titration?

when we do not know nothing about the other titrant.


Why is phenolphthalein an appropiate indicator for back titration?

Phenolphthalein is appropriate for back titration because it undergoes a color change in a specific pH range (pH ~8.2-10), making it useful for detecting excess acid or base after a reaction is complete. In back titrations, where the analyte is in excess and the titrant is limited, phenolphthalein helps determine the amount of excess analyte present by signaling the endpoint of the reaction.


What are different types of EDTA titration?

1. Direct Titration In direct titration, you simply add an indicator to the solution of the metal ion and titrate with EDTA. Before starting the titration,it is needed to check that the pH of the solution to obtain a good formation constant value and on the other hand indicator colour change as well. 2.Indiract titration EDTA can be used as titrant for anions. Anions can be precipitated with suitable metal ion. Filter and wash the ppt with proper solution. Then boil in excess EDTA to complex metal ion(ppt). Back titrate to determine how much metal ion you had. 3.Back Titration In a back titration an excess of EDTA is added to the metal ion solution, and the excess EDTA is titrated with a known concentration of a second metal ion. The second metal ion must form a weaker complex with EDTA than the analyte ion so the second metal does not displace the analyte ion from its complex with EDTA. 4.Displacement titration Here the analyte is treated with an excess of a second metal bound to EDTA. The analyte ion displaces the second metal from the EDTA complex, and then the second metal is titrated with EDTA.


How do you check the alcohol percentage in wine?

Using a method called back-titration, the alcohol concentration of a grape wine can be determined. Just google steps and procedure of back-titration and find out what standard solution and indicator you will need. :)


What is a back titration?

A back titration is a technique used in analytical chemistry to determine the concentration of an analyte by reacting it with an excess of a known reagent, then back-titrating the remaining excess reagent. This method is useful when the analyte reacts slowly or incompletely with the titrant in a direct titration.


Why in back titration blue to red end point appears?

In back titration, a blue to red end point can appear due to the presence of an indicator that changes color in response to the excess titrant added after reacting with the analyte. The change in color indicates the completion of the reaction between the excess titrant and the analyte, enabling the determination of the analyte's concentration.


Why back titration is used in complexometric titration?

Back titration is used in complexometric titration when the analyte reacts slowly with the titrant or when a direct titration is not feasible due to interference from other substances. By adding an excess of a known reagent to react with the analyte, followed by titration with another reagent to determine the excess, the concentration of the analyte can be accurately calculated.


What are the two indirect method of titration?

The two indirect methods of titration are back titration and reverse titration. In back titration, an excess of a reagent is added to react with the analyte, and then the unreacted excess is titrated to determine the amount that reacted with the analyte. In reverse titration, a standard solution is first added to a known amount of analyte to react completely, and then the excess standard solution is titrated back to determine the amount that reacted with the analyte.