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Solid calcium chloride, the form most often encountered, CaCl2 is ionic. the anhydrous form is a dliquescent, it absorbs large amounts of water and is sometimes used as drying agent, a dessicant.

Molecular CaCl2 is a linear molecule as precicted by VSEPR, and the Ca-Cl bond is polar but the bond dipoles cancel each other so the molecule has no dipole moment.

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