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is there a sweet smell? Does the coolant level drop in the overflow tank and/or the radiator? if so, you might be looking at a bad head gasket. if there is slight white smoke(usually condensation) and no loss of coolant, then it is normal. once the engine (and exhaust system) gets hot, there should be no more smoke. if the smoke has a bluish tint it could be valve seals leaking. the best thing to do is take it to a garage just about when they close and leave the car with instructions to check the smoke coming from the exhaust the next morning. just about any tech. i know of can identify whether there is a head gasket leak, valve seal leak, or normal condensation burn off just by seeing it start cold!

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Q: Is it normal for white smoke to come out of the exhaust at startup of a 2000 Rav 4 when the weather is cold?
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