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Very sharp objects are typically dangerous unless used properly. As I cannot think of a proper way to use broken window pane I would say yes, it's dangerous on clothes and materials. If this is some sort of art project or house renovation, I would suggest using very thick gloves when handling the broken glass. Not mittens or gardening gloves, but gloves meant for handling dangerous materials. I would also take great care when handling the broken glass even when wearing protective gloves.

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