kmno4 is very good oxidizing agent. that means it is easily reduced by any other reagent. so it can't be considered as primary standard as its concentration changes upon free leaving
I suppose that the potassium permanganate is not contained in the list of NIST standards.
aqueous solutions are not stable for long
E Mohr salt 392/1
discussion for the titration of NaOH and HNO3 by using phenolphthalein & methyl orange indicators
As we all know that the potassium permanganate (KMnO4) is the dark purple color solution ...and in titration it become colorless ....so when the titration is completed ...and the other single drop of KMnO4 solution produce pinkish colour in a beaker ...which indicate that the reaction was completed just a single drop before .. we use indicator in a a reaction in order to indicate ...but we dont used indicator in titration with KMnO4 because it also indicate us by changing its color ...colorless to pink
Not usually. Potassium iodide is usually present in a large excess. It is usually the potassium iodate that is the limiting ingredient.
The former is a acid base neutralisation reaction whereas the latter is a redox reaction.
Usually there is no indicator needed in potassium permanganate titrations as there will be an excess of manganate ions in the conical flask, turning the solution from colourless to pale pink.
The indicator is used to measure the end point of titration. Methyl red and phenolphthalein are frequently used indicators in acid-base titration. Potassium permanganate can used as a self indicator in redox titrations where applicable.
Usually there is no indicator needed in potassium permanganate titrations as there will be an excess of manganate ions in the conical flask, turning the solution from colourless to pale pink.
If the temperature is too low (below 55 degrees celsius), the interaction between the oxalate and the potassium permanganate will move too slow as to be used as a practical lab experiment. *** Above 60 degrees celsius, oxalate acid begins to decompose, so it's important to stay in this range.
because if the temperature is too low the interaction between the oxylate and potassium permanganate will move too slow?? why IDK
as it is pink in colour so no external agent is required for titration when we titrate againist another component it will changes it colour to pale pink asd it is end point
for preparing 0.1 normal solution of potassium permanganate you have to disssolve 3.16 g potssium permangnate in 1L water bt in alkaline or neutral medium reactions of potassium permanganate is different and Mn gains 3 electrons in redox reaction,so far alkaline medium redox titration equivalent wt of KMnO4 will be 158\3=52.6.so far,0.1 N KMnO4 in alkaline medium redox titration dissolve 5.26 g in 1L sol.
The permanganate ion, MnO4- purple in colour. The sulfuric acid is added to create acidic conditions. In acidic conditions, the MnO4- gets reduced to Mn2+ which is colourless. Therefore, judging by the colour change, we can figure out how much of the potassium permanganate has been used.
This is because in acidic medium kmn04 decomposes to give Mn2+ ions which impart pink colour to the solution. The reaction being Mno4- +8H+5e ----->Mn2+ + 4H2O
Nitric acid, being a strong oxidising agent, interferes with oxidising capacity of KMnO4 hence reducing accuracy of titration.
To act as a catalyst
potassium dichromate