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kmno4 is very good oxidizing agent. that means it is easily reduced by any other reagent. so it can't be considered as primary standard as its concentration changes upon free leaving

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12y ago
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13y ago

I suppose that the potassium permanganate is not contained in the list of NIST standards.

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aqueous solutions are not stable for long

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Q: Why is potassium permanganate used in titration experiment despite being a secondary standard solution?
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Why no use indicator in the standardizing potassium permanganate titration?

Usually there is no indicator needed in potassium permanganate titrations as there will be an excess of manganate ions in the conical flask, turning the solution from colourless to pale pink.


The purpose of an indicator in a titration experiment?

The indicator is used to measure the end point of titration. Methyl red and phenolphthalein are frequently used indicators in acid-base titration. Potassium permanganate can used as a self indicator in redox titrations where applicable.


What type of indicator is used during potassium permanganate titration?

Usually there is no indicator needed in potassium permanganate titrations as there will be an excess of manganate ions in the conical flask, turning the solution from colourless to pale pink.


Why potassium oxalate is acidified before titration?

If the temperature is too low (below 55 degrees celsius), the interaction between the oxalate and the potassium permanganate will move too slow as to be used as a practical lab experiment. *** Above 60 degrees celsius, oxalate acid begins to decompose, so it's important to stay in this range.


Why do you have to warm the oxalate solution before performing titration?

because if the temperature is too low the interaction between the oxylate and potassium permanganate will move too slow?? why IDK


Why Potassium permanganate act as self indicator?

as it is pink in colour so no external agent is required for titration when we titrate againist another component it will changes it colour to pale pink asd it is end point


How do you prepare standard solution of potassium dichromate to compare icteric index of serum?

for preparing 0.1 normal solution of potassium permanganate you have to disssolve 3.16 g potssium permangnate in 1L water bt in alkaline or neutral medium reactions of potassium permanganate is different and Mn gains 3 electrons in redox reaction,so far alkaline medium redox titration equivalent wt of KMnO4 will be 158\3=52.6.so far,0.1 N KMnO4 in alkaline medium redox titration dissolve 5.26 g in 1L sol.


Why KMnO4 titration's are carried out only in the presence of dilute H2SO4?

The permanganate ion, MnO4- purple in colour. The sulfuric acid is added to create acidic conditions. In acidic conditions, the MnO4- gets reduced to Mn2+ which is colourless. Therefore, judging by the colour change, we can figure out how much of the potassium permanganate has been used.


Why titration of potassium permanganate is carried out in acidic medium?

This is because in acidic medium kmn04 decomposes to give Mn2+ ions which impart pink colour to the solution. The reaction being Mno4- +8H+5e ----->Mn2+ + 4H2O


In permanganate titration's why is nitric acid not used?

Nitric acid, being a strong oxidising agent, interferes with oxidising capacity of KMnO4 hence reducing accuracy of titration.


Why do you have to heat up the solution of oxalic acid after adding sulphuric acid for the titration with permanganate?

To act as a catalyst


Which one is better for titration with Ferrous Ammonium Sulphate potassium dichromate or potassium permaganate and why?

potassium dichromate