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LiOH is Li+ OH- and the bond here is ionic. In OH- the hydrogen atom is covalently bonded to oxygen.

An advanced point is that Li salts are well known to have some covalent character. this is due to the size of the Li ion which is smaller than the other members of group 1 and is therefore more polarizing that is to say it distorts the electron cloud on the anion. This is quite marked in the halides where the solubility is less than expected.

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11y ago
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1w ago

LiOH is an ionic compound composed of lithium (Li) cation and hydroxide (OH) anion. The bond between Li and OH in LiOH is predominantly ionic because lithium donates its electron to form a cation, while the hydroxide ion accepts the electron to form an anion. Covalent bonds involve sharing of electrons, which is not the case in LiOH.

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Q: LiOH is it both a ionic and covalent bond?
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