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Caltrop (Tribulus terrestris) causes hepatogenous photosensitisation, basically it affects the liver and phylloerythrin accumulates in the peripheral blood vessels leading to very bad 'sunburn'. Remove the sheep from access to the plant provide good quality water and hay and shade - if it is really bad you might need some antihistamines from a veterinarian.

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Q: Need remedy for calthrop poisoning in sheep?
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