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Depends of the type of fire extinguisher.

Common CO2-extinguishers are filled with with compressed CO2. Once released it cooles down the fire below it's burning- or ignition-temperature and replaces the Air. The lack of oxigens will then suffocate the fire.

No matter what type of extinguisher, it's always about cooling of suffocating the flame.

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Q: On What common principle do all fire extinguishers work?
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