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Each cell of a battery has a predefined voltage, and for a given type of battery, a predefined maximum current capability. Putting cells in series, just like putting batteries in series, increases the voltage (1 AAA battery = 1.5 volts, 2 AAA batteries in series = 3 volts). Putting cells in parallel increases the amount of current that can be drawn from them (1 cell = 1 cell max. current, 2 cells in parallel = 2 cells worth max current). Note available power will be the same (P = V*I), so whether you use a series or parallel connection usually depends upon the desired output voltage.

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