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The rate of effusion is inversely proportional to the square root of the molar mass (Graham's Law).
Put another way, the small, lighter weight gas will move faster than the heavier gas.
Molar mass CH4 = 16 g/mol.
Molar mass SO2 = 48 g/mol
Thus, CH4 will move faster.

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Q: Two gases CH4 and SO2 effuse through a tiny opening. Which will move faster?
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