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the same way an insulator and a conductor will work with out the electron theory!

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14y ago

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Why does the free electron theory fail to predict the semiconducting properties of materials?

Drawbacks of Classical free electron theory:1. It is macroscopic theory2. This theory cannot explain the electron conductivity ofsemiconductors and insulators.3. Ferromagnetism cannot be explained by this theory.4. This theory cannot explain the Photoelectric effect, Comptoneffect and the Black Body radiation.5. The calculated value of specific heat of metals is not matchingwith the experimental value.6. At low temperature, Lorentz number is not a constant. But by12classical theory it is a constant.7. Dual nature cannot be explained.8. Atomic fine spectra cannot be explained.9. Classical theory states that all the free electrons will absorbenergy, but quantum theory states that only few electrons willabsorb energy


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What is quantum free electron theory of metal?

Classical free electron theory could not explain many physical properties. In 1928, Sommerfeld developed a new theory applying quantum mechanical concepts and Fermi-Dirac statistics to the free electrons in the metal. This theory is called quantum free electron theory.


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Is there a unified theory explaining all correlated electron systems?

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