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nirto benzene form coating on the ppts ; hence we can avoid the direct reaction between the ppts and added thiocynate solution. this will minimize the error in titration. Because the added thiocynate must react with only FREE chloride ions.
AgNO3 + KI ----> AgI(ppts.) + KNO3
No specific colour only white ppts. are formed
the equation is, NaBr + AgNO3 = AgBr(pale yellow ppts) + NaNO3(aq.)
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all the organic compounds and nitrates of metals and ammonium do not form ppts with silver nitrate.
Book Title: Simplified Approach of DBMS Publisher: Kalyani PPTs are available on request to parteek_bhatia@hotmail.com
Both these nitrates are water soluble when H2S is added in both the solutions Lead forms black ppts. while silver does not.
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